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I just found this and thought it was interesting. I might try it.
Make Your Own Insecticide
Red pepper spray is a good general insecticide and is especially effective against caterpillars. You’ll have to use this homemade spray more often than a chemical spray, but it’s much gentler on the environment. For your own safety, wear gloves when handling peppers and pepper spray.
Red Pepper Spray Concentrate:
1 unpeeled onion
1 unpeeled head of garlic
1 tablespoon cayenne pepper
3 pints water
1. Chop onion and garlic and combine all ingredients in a saucepan. Simmer 20 minutes.
2. Cool and store in jars in the refrigerator for 6 weeks.
3. Strain and store in jars.
To use, dilute 1 tablespoon of concentrate with 1 pint of water. Add a little Ivory snow. Shake and spray on plant.