Although your overall temperature will be higher all day after you ovulate, things like drinking, walking, showering, etc will make that jump drastically all over the place. That's why it's best to do it after 4 hours of rest (ie. the same time every morning) just to be sure that what you're seeing isn't artificial. Doing it in the afternoon won't be accurate enough to be sure of anything unless you've spent a few hours before that laying on the couch, not lifting a finger, and not having anything to eat or drink! Since most of us aren't in that situation, we do it first thing in the morning!