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OPK's are sometimes able to pick up HCG earlier than a HPT because HCG and LH are very similar in composition and OPK's are much more sensitive.
That being said however, if it's definitely showing a positive, (Test line just as dark or darker than the control) you should be seeing something on a HPT by now. It sounds more like your O was pushed back for some reason. Are you absolutely 100% sure that you O'd when you did?