Mine does this too, and I think I've determined that it's an excess of lipase, like Erin posted above. It breaks down the milk fat and starts the digestive process sooner. So that makes it go rancid faster. The only solution I found online was to scald the milk before freezing it or storing it in the freezer (so bringing it just to before a boil on the stove). It stops the lipase from breaking down the milk. Unfortunately for me, I've stopped pumping, and all my milk is freezer stash now. So our only solution is to only thaw the milk immediately before feeding it to Sean. And to always double check that it's not already spoiled. Most of it still smells chalky, but that isnt' a problem for the baby, as long as they don't mind the slightly altered taste. The only problem is if it has indeed gone rancid.